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Unexpected Formation of (E)-4-Alkene 1,3-Diketones from the Three-Component Reaction of Lithium Selenolates with 1-(1-Alkynyl)cyclopropyl Ketones and Aldehydes

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Unexpected_Formation_of_i_E_i_4_Alkene_1_3_Diketones_from_the_Three_Component_Reaction_of_Lithium_Selenolates_with_1_1_Alkynyl_cyclopropyl_Ketones_and_Aldehydes/2630174
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A novel three-component stereoselective synthesis of (E)-4-alkene 1,3-diketones from lithium selenolates, 1-(1-alkynyl)cyclopropyl ketones, and aldehydes is reported. This reaction afforded the products in moderate to good yields with the formation of a new C–Se single bond, a new C–C double bond, and a new C–O double bond.
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2016-02-23
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