Biomimetic Models for the Active Site of [Fe]Hydrogenase Featuring an Acylmethyl(hydroxymethyl)pyridine Ligand
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https://figshare.com/articles/dataset/Biomimetic_Models_for_the_Active_Site_of_Fe_Hydrogenase_Featuring_an_Acylmethyl_hydroxymethyl_pyridine_Ligand/2505355
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The first acylmethyl(hydroxymethyl)pyridine ligand-containing [Fe]hydrogenase model complexes 2–4 have been synthesized starting from the nucleophilic substitution reaction of 2-(4-MeC6H4SO3CH2)-6-HOCH2C5H3N with Na2Fe(CO)4. While the reaction course for producing complex 3 via the highly unstable intermediate complex 1 is monitored by in situ IR spectroscopy, the isolated model complexes 2–4 are fully characterized.
创建时间：
2016-02-20
