five

Mild and Selective Reduction of Imines: Formation of an Unsymmetrical Macrocycle

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https://figshare.com/articles/dataset/Mild_and_Selective_Reduction_of_Imines_Formation_of_an_Unsymmetrical_Macrocycle/3312826
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During investigations of 5, a [3 + 3] Schiff-base macrocycle with six imines, a partially reduced Schiff-base macrocycle, 6, possessing one CH2NH and five imine groups was obtained. Control experiments and deuterium labeling indicate that the macrocycle is reduced by a benzimidazoline generated during the reaction. Benzimidazolines may be convenient reagents for the mild and selective reduction of imines.
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2004-12-10
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