Anion-Dependent Self-Assembly of Near-Infrared Luminescent 24- and 32-Metal Cd–Ln Complexes with Drum-like Architectures
收藏acs.figshare.com2023-06-05 更新2025-03-25 收录
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https://acs.figshare.com/articles/dataset/Anion_Dependent_Self_Assembly_of_Near_Infrared_Luminescent_24_and_32_Metal_Cd_Ln_Complexes_with_Drum_like_Architectures/2405983/1
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Two series of 4d–4f clusters
[Ln8Cd24L12(OAc)48] and [Ln6Cd18L9Cl8(10)(OAc)28(26)] (Ln = Nd, Gd, Er, and Yb) with novel
drum-like structures were
prepared using a flexible Schiff base ligand. Their NIR luminescence
properties were determined.
采用柔性的席夫碱配体，成功制备了两种新型的4d-4f簇系列化合物[Ln8Cd24L12(OAc)48]和[Ln6Cd18L9Cl8(10)(OAc)28(26)]（其中Ln代表Nd、Gd、Er和Yb），它们具有独特的鼓状结构。对这些化合物的近红外发光特性进行了测定。
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