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A Highly Efficient Catalyst for Selective Oxidative Scission of Olefins to Aldehydes: Abnormal-NHC–Ru(II) Complex in Oxidation Chemistry

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Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Highly_Efficient_Catalyst_for_Selective_Oxidative_Scission_of_Olefins_to_Aldehydes_Abnormal_NHC_Ru_II_Complex_in_Oxidation_Chemistry/2247526
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The utility and selectivity of the catalyst [Ru­(COD)­(L1)­Br2] (1) bearing a fused π-conjugated imidazo­[1,2-a]­[1,8]­naphthyridine-based abnormal N-heterocyclic carbene ligand L1 is demonstrated toward selective oxidation of CC bonds to aldehydes and CC bonds to α-diketones in an EtOAc/CH3CN/H2O solvent mixture at room temperature using a wide range of substrates, including highly functionalized sugar- and amino acid-derived compounds.
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2016-02-16
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