LaSr3F5(CN2)2: A Prototype Structure for Mixed-Valent Eu4F5(CN2)2
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/LaSr_sub_3_sub_F_sub_5_sub_CN_sub_2_sub_sub_2_sub_A_Prototype_Structure_for_Mixed_Valent_Eu_sub_4_sub_F_sub_5_sub_CN_sub_2_sub_sub_2_sub_/2464618
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The new compound LaSr3F5(CN2)2 was prepared and structurally characterized as a prototype structure for the remarkably distorted mixed-valent compound Eu4F5(CN2)2, which contains four distinct europium ions in the structure: one Eu3+ and three Eu2+. Instead of repeating the given distorted structural pattern, LaSr3F5(CN2)2 forms a structure which can be considered as an ideal high-symmetry structure for Eu4F5(CN2)2, due to the occupation of La3+ and Sr2+ ions on one and the same crystallographic position. The crystal symmetry of this structure is an interesting issue to compare with what has been previously proposed.
创建时间：
2016-02-20
