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Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions

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https://figshare.com/articles/dataset/Microporous_Pillared_Paddle_Wheel_Frameworks_Based_on_Mixed_Ligand_Coordination_of_Zinc_Ions/3278068
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The reaction of Zn(NO3)2·6H2O, various dicarboxylic acids, and either 4,4‘-bipyridine or N,N‘-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.
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2016-05-05
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