Readily Accessible Unsymmetrical Unsaturated 2,6-Diisopropylphenyl N‑Heterocyclic Carbene Ligands. Applications in Enantioselective Catalysis
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https://figshare.com/articles/dataset/Readily_Accessible_Unsymmetrical_Unsaturated_2_6-Diisopropylphenyl_N_Heterocyclic_Carbene_Ligands_Applications_in_Enantioselective_Catalysis/4609846
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资源简介：
A new
multicomponent procedure was applied to the synthesis of
(a)chiral bulky unsymmetrical unsaturated 2,6-diisopropylphenyl N-heterocyclic
carbene (NHC) precursors with excellent selectivity (up to 95%) and
good yields. This approach offers access to new chiral NHC ligands,
which have found successful applications in both copper-catalyzed
asymmetric allylic alkylation and copper-catalyzed asymmetric borylation.
创建时间：
2017-02-02
