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Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange

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NIAID Data Ecosystem2026-03-09 收录
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An ‘arene exchange’ approach has been successfully applied for the first time to the synthesis of Ru(II)-based ‘tethered’ reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.

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2015-12-16
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