Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks
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https://figshare.com/articles/dataset/Selective_Solvent_Assisted_Linker_Exchange_SALE_in_a_Series_of_Zeolitic_Imidazolate_Frameworks/2145139
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资源简介：
Solvent-assisted
linker exchange (SALE) has recently emerged as an attractive strategy
for the synthesis of metal–organic frameworks (MOFs) that are
unobtainable via traditional synthetic pathways. Herein we present
the first example of selective SALE in which only the benzimiadazolate-containing
linkers in a series of mixed-linker zeolitic imidazolate frameworks
(ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10,
SALEM-10b, and SALEM-11, respectively) are isostructural to the parent
framework and in each case contain trifluoromethyl moieties. We therefore
evaluated each of these materials for their hydrophobicity in condensed
and gas phases. We expect that selective SALE will significantly facilitate
the design of improved, and potentially complex, MOF materials with
new and unusual properties.
创建时间：
2016-02-13
