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“Oxide Route” for the Preparation of Mercury(II) N-Heterocyclic Carbene Complexes

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Oxide_Route_for_the_Preparation_of_Mercury_II_N_Heterocyclic_Carbene_Complexes/2692435
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Imidazolium salts react with HgO to give mono-NHC dihalomercury(II) complexes in acceptable yields. The solid-state structures of several examples were determined by X-ray diffraction. The complexes consist of monomeric (NHC)HgX2 units, which feature tricoordinated mercury atoms, a structural arrangement rarely found for mercury compounds.
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2016-02-23
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