Palladium-Catalyzed Selective Fluorination of <i>o</i>‑Carboranes
收藏NIAID Data Ecosystem2026-03-09 收录
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A Pd(II)-catalyzed direct selective fluorination reaction of carboranes using a F+ reagent has been developed, leading to a series of polyfluorocarboranes in high isolated yields. The mechanism involving electrophilic B–H activation, oxidation of Pd(II) by F+ species, and reductive elimination is proposed.
创建时间：
2016-02-19
