σ-Alane Complexes of Chromium, Tungsten, and Manganese
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Alane_Complexes_of_Chromium_Tungsten_and_Manganese/2551825
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Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ1 σ-alane complexes featuring Al–H bonds bound to [W(CO)5] and [Cp′Mn(CO)2] fragments, together with a related κ2 complex of [Cr(CO)4]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as σ-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.
创建时间：
2016-02-22
