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Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes

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NIAID Data Ecosystem2026-03-06 收录
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Iridium complexes supported by the PNP amidophosphine scaffold (PNP = [N(2-PiPr2-4-Me-C6H3)2]−) perform the selective double C−H activation of methyl amines to produce iridium(III) dihydrido aminocarbenes. The reactivity of these complexes is presented and contrasted with that observed for the previously reported iridium(I) alkoxycarbenes.

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2016-02-27
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