Crystal or Low Molecular Mass Organogel Based on Sugar-Derived Chiral Pyrano[2,3-<i>b</i>]naphtho[1,2-<i>e</i>]pyrans

2-C-Acetoxymethyl glycal derivatives reacted with β-naphthol in the presence of InCl3 (30 mol %) to give chiral pyrano[2,3-b]naphtho[1,2-e]pyrans in good to excellent yields via stereoselective Ferrier rearrangement−tandem cyclization. The major glucose-derived product exhibited crystal packing with C−H···O and C−H···π (arene) interactions and the major galactose-derived product, a low molecular mass organogelator (LMOG), formed a rare type of micro tubular gel assembly in n-hexane.