Alkane Dehydrogenation by C–H Activation at Iridium(III)
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https://figshare.com/articles/dataset/Alkane_Dehydrogenation_by_C_H_Activation_at_Iridium_III_/2431765
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资源简介：
Stoichiometric alkane dehydrogenation utilizing an IrIII pincer complex, (dmPhebox)Ir(OAc)2(OH2) (1a), has been described. The
reaction between 1a and octane resulted in quantitative
formation of (dmPhebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major
product, indicative of terminal C–H activation by 1a. In contrast to prior reports of alkane dehydrogenation with Ir,
C–H bond activation occurs at IrIII and the dehydrogenation
is not inhibited by nitrogen, olefin, or water.
创建时间：
2016-02-19
