[(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>U(Me)(OTf)]<sub>2</sub>: A New Reagent for Uranium Metallocene Chemistry. Preparation of the First Actinide Hydrazonato Complexes
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The synthesis and characterization of the first actinide hydrazonato complex, (C5Me5)2U(η2(N,N‘)-CH3NNCPh2)(OTf) (3), has been made possible by use of the organouranium(IV) trifluoromethanesulfonate (triflate) complex [(C5Me5)2U(CH3)(OTf)]2 (2; OTf = OSO2CF3), which is derived from the reaction between (C5Me5)2U(CH3)2 and Ph3COTf. The related chemistry for (C5Me5)2U(CH3)(Cl) is also reported. All new complexes have been structurally characterized.
创建时间：
2016-08-26
