Development of New P‑Chiral P,π-Dihydrobenzooxaphosphole Hybrid Ligands for Asymmetric Catalysis
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A new family of P-chiral P,π-hybrid ligands was prepared from the dihydrobenzooxaphosphole core. These new ligands were demonstrated to be both sterically and electronically tunable at the substituents on the phosphorus atom and the π-system of the ligand. Application of these new ligands to the catalytic asymmetric addition of boronic acids to imine electrophiles was shown to proceed with high levels of enantioinduction.
创建时间：
2016-02-16
