Reversible Olefin−Hydride Insertion in the Cationic Ruthenium Complexes [(η<sup>6</sup>-C<sub>6</sub>H<sub>5</sub>CH<sub>2</sub>CH<sub>2</sub>PR<sub>2</sub>)RuH(CH<sub>2</sub>CH<sub>2</sub>)]<sup>+</sup>
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Ruthenium−hydride olefin complexes having the formula [(η6-C6H5CH2CH2PR2)RuH(CH2CH2)][PF6], where R = Cy (1) and Ph (2), were prepared via the reaction of triphenylcarbenium hexafluorophosphate (Ph3CPF6) with the corresponding (η6-C6H5CH2CH2PR2)Ru(CH3)2 complexes. Reversible olefin−hydride insertion reactions were directly observed for both 1 and 2 by 2D EXSY magnetic resonance experiments. The structure of complex 1 was determined by X-ray crystallography.
创建时间：
2016-05-07
