Activation of Nitrous Oxide by Dinuclear Ruthenium Complexes
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https://figshare.com/articles/dataset/Activation_of_Nitrous_Oxide_by_Dinuclear_Ruthenium_Complexes/2476144
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资源简介：
The dinuclear Ru(II) complexes (arene)Ru(μ-Cl)3RuCl(C2H4)(PCy3) (arene = p-cymene or 1,3,5-C6H3iPr3) react with N2O under mild conditions to
give OPCy3 and the trinuclear complexes (arene)Ru(μ-Cl)3Ru(μ-Cl)3Ru(arene). The N-heterocyclic carbene
complex (p-cymene)Ru(μ-Cl)3RuCl(C2H4)(IMes) (IMes = 1,3-dimesitylimidazol-2-ylidene),
on the other hand, reacts with N2O to give a mixed-valence
Ru(II)/Ru(III) complex with a chelating alkoxy ligand. Dinitrogen
complexes were identified as intermediates in all reactions. At elevated
temperature, the carbene complex (p-cymene)Ru(μ-Cl)3RuCl(C2H4)(IMes) is able to catalyze the oxidation of
alcohols with N2O.
创建时间：
2016-02-20
