Tropospheric Ozone Assessment Report: Tropospheric ozone from 1877 to 2016,...
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https://data.ucar.edu/dataset/tropospheric-ozone-assessment-report-tropospheric-ozone-from-1877-to-2016-observed-levels-trend1
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From the earliest observations of ozone in the lower atmosphere in the 19th century, both measurement methods and the portion of the globe observed have evolved and changed....
