Reactivity Studies of Rhodium(III) Porphyrins with Methanol in Alkaline Media
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https://figshare.com/articles/dataset/Reactivity_Studies_of_Rhodium_III_Porphyrins_with_Methanol_in_Alkaline_Media/2841148
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资源简介：
Rh(ttp)Cl (1a) (ttp = 5,10,15,20-tetrakistolylporphyrinato dianion) was found to react with methanol at a high temperature of 150 °C in the presence of inorganic bases to give a high yield of Rh(ttp)CH3 (2a), up to 87%. Rh(ttp)H (1d) is suggested to be the key intermediate for the carbon−oxygen bond cleavage.
创建时间：
2009-07-27
