“Clickphine”: A Novel and Highly Versatile P,N Ligand Class via Click Chemistry
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A novel P,N-type ligand family (ClickPhine) is disclosed that is easily accessible using the Cu(I)-catalyzed azide−alkyne “click” cycloaddition. A diverse set of ligands was made in just three steps from readily available starting materials to give several homogeneous and a heterogeneous catalyst. Preliminary experiments show the efficacy of these ligands in the Pd-catalyzed allylic alkylation reaction.
创建时间：
2016-03-01
