Palladium-Catalyzed Approach to Stereodefined Ten-Membered Cycles from 1,5-Bisallenes
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A three-component Pd(0)-catalyzed reaction of 1,5-bisallenes with organic halides in the presence of primary amines was observed to afford stereodefined not readily available ten-membered cyclic compounds highly chemo- and regioselectively. A mechanism involving two π-allylic palladium intermediates was proposed to account for the observed regio- and stereoselectivity.
创建时间：
2011-10-07
