Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity
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Two salts with one-dimensional, SiS2-type telluridostannate chain anions {[MSnTe4]2–}n, Rb2[HgSnTe4] (2) and (NMe4)2[MnSnTe4] (3), were prepared by the reactions of [SnTe]4– anions with Hg2+ or Mn2+ ions in solution. We present the crystal structures of 2 and 3, as well as the magnetic properties of the previously reported Cs+ analogue Cs2[MnSnTe4] (1).
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2016-02-21
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