Pd-Catalyzed Arylation Reactions with Phenol Diazonium Salts: Application in the Synthesis of Diarylheptanoids
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Pd_Catalyzed_Arylation_Reactions_with_Phenol_Diazonium_Salts_Application_in_the_Synthesis_of_Diarylheptanoids/2655616
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The first total synthesis of the natural product (3S,7R)-5,6-dehydro-de-O-methyl centrolobine and various analogues is reported, using a highly regio- and diastereoselective Mizoroki−Heck reaction of phenol diazonium salts and enantiopure dihydropyrans. The assigned relative configuration was confirmed by single-crystal X-ray structure analysis, but a revision of the absolute configuration is proposed based on polarimetric measurement.
创建时间：
2016-02-23
