Photochemical Water Oxidation and Origin of Nonaqueous Uranyl Peroxide Complexes
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https://figshare.com/articles/dataset/Photochemical_Water_Oxidation_and_Origin_of_Nonaqueous_Uranyl_Peroxide_Complexes/2310544
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资源简介：
Sunlight
photolysis of uranyl nitrate and uranyl acetate solutions
in pyridine produces uranyl peroxide complexes. To answer longstanding
questions about the origin of these complexes, we conducted a series
of mechanistic studies and demonstrate that these complexes arise
from photochemical oxidation of water. The peroxo ligands are easily
removed by protonolysis, allowing regeneration of the initial uranyl
complexes for potential use in catalysis.
创建时间：
2016-02-17
