Molecular Paneling in the Rational Design of Calixarene Coordination Polymers
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We demonstrate the design of calixarene coordination polymers by using versatile molecular panels comprising binuclear Co(II) clusters and p-carboxylatocalix[4]arenes linked together with 4,4′-bipyridyls. By variation in the length of the 4,4′-bipyridyl, conformational changes in the calixarene molecule have been observed and the solvent-filled channels within the crystalline solid have been adjusted.
创建时间:
2016-02-19



