Anti-Markovnikov Hydroamination of Homoallylic Amines
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https://figshare.com/articles/dataset/Anti_Markov_nikov_Hydroamination_of_Homoallylic_Amines/2114059
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资源简介：
The
development of an anti-Markovnikov-selective hydroamination
of unactivated alkenes is a significant challenge in organometallic
chemistry. Herein, we present the rhodium-catalyzed anti-Markovnikov-selective
hydroamination of homoallylic amines. The proximal Lewis
basic amine serves to promote reactivity and enforce regioselectivity
through the formation of the favored metallacycle, thus over-riding
the inherent reactivity of the alkene. The scope of both the amine
nucleophiles and homoallylic amines that participate in the
reaction is demonstrated.
创建时间：
2016-02-12
