Construction of a Three-Dimensional Polynuclear Zinc Compound Based on Unique Metallophthalocyanine-like Subunits
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A polynuclear zinc compound, [Zn7(BTA)7(OABDC)(μ3-OH)2(μ2-OH)2·H2O] (1), has been prepared by using benzotriazole (HBTA) and 5-oxyacetatoisophthalic acid (H3OABDC) as ligands under hydrothermal conditions. For compound 1, an unprecedented metallophthalocyanine-like “Zn2(μ3-OH)2⊂[Zn4BTA4]” subunit is constructed from η3-BTA ligands and Zn atoms and further linked via μ2-OH, outer four-connected Zn atoms, and 5-oxyacetateisophthalic acid to form a novel three-dimensional framework.
创建时间：
2016-02-26
