遇见数据集

Synthetic Access to Bent Polycycles by Cation-π Cyclization

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NIAID Data Ecosystem2026-03-06 收录
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The presence of an ether oxygen within a chain undergoing cation−polyene cyclization has a profound influence on the stereochemistry of this important construction, apparently due to nucleophilic participation of oxygen in the cyclization process and formation of an oxonium intermediate, leading to bent fused ring systems.

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2016-02-24
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