Remarkable Metal-Complexed Phosphorus Analogues of the Cyclopropenylcarbene–Cyclobutadiene Rearrangement
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In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.
创建时间:
2016-02-23



