Palladium and Molybdenum Complexes of the Heteroleptic Organostannylene [2,6-(Me<sub>2</sub>NCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>]SnCl
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The synthesis and molecular structures are reported for the transition metal heteroleptic organostannylene complexes {[2,6-(Me2NCH2)2C6H3]SnCl}(C5H5)(CO)2MoCl (6) and {[2,6-(Me2NCH2)2C6H3]Sn(OAc)}Pd(Cl)[2-(Me2NCH2)C6H4] (7). It is shown that the intramolecularly coordinated heteroleptic organostannylene [2,6-(Me2NCH2)2C6H3]SnCl undergoes a redox-type reaction with Pd(PPh3)4 to give cis-[2,6-(Me2NCH2)2C6H3]SnCl}2PdCl2.
创建时间：
2016-02-26
