Learning about Steric Effects in NHC Complexes from a 1D Silver Coordination Polymer with Fréchet Dendrons
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https://figshare.com/articles/dataset/Learning_about_Steric_Effects_in_NHC_Complexes_from_a_1D_Silver_Coordination_Polymer_with_Fre_chet_Dendrons/2329411
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资源简介：
The
complex (NHC)AgBr, which bears G1 poly(benzyl ether) dendritic substituents
in the NHC ligand, forms a 1D coordination polymer based on unusual
zigzag −Ag–halide– chains. The asymmetric distribution
of the volume buried by the NHC ligand in the Ag coordination sphere
is important to explain the formation of this structure. A Vbur eccentricity parameter has been introduced
and used in conjunction with the %Vbur descriptor to analyze the X-ray structures of 100 (NHC)AgX complexes.
创建时间：
2014-01-27
