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Metal-Assisted Aldol-Type Condensation of Two Acetimino Ligands To Give a 4-Imino-2-methylpentan-2-amino Rhodium(III) Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Metal_Assisted_Aldol_Type_Condensation_of_Two_Acetimino_Ligands_To_Give_a_4_Imino_2_methylpentan_2_amino_Rhodium_III_Complex/3268774
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资源简介:
The intramolecular aldol-like condensation of two acetimino ligands has been observed for the first time to occur in [Rh(Cp*)Cl(NHCMe2)2]ClO4 (1·ClO4), under catalytic or stoichiometric reaction conditions, to give [Rh(Cp*)Cl{N,N-NHC(Me)CH2C(Me)2NH2}]X (2·X, X = Cl, ClO4). The crystal structures of 1·ClO4 and 2·Cl have been determined.
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2016-05-05
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