Polymerization of Ethylene by the Electrophilic Heteroscorpionate-Containing Complexes [TiCl<sub>3</sub>(bdmpza)] and [TiCl<sub>2</sub>(bdmpza){O(CH<sub>2</sub>)<sub>4</sub>Cl}] (bdmpza = Bis(3,5-dimethylpyrazol-1-yl)acetate)
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Novel heteroscorpionate-containing titanium complexes, TiCl3(bdmpza) and TiCl2(bdmpza){O(CH2)4Cl} (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate), have been prepared. Toluene solutions of these complexes with methylaluminoxane catalyze the polymerization of ethylene and show a high catalytic activity.
创建时间：
2016-08-26
