Complexes of Ruthenium(II) with Unsymmetrical Diphosphines and Diphosphinomethanides. A Way to Synthesize Chiral Metallodiphosphines
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https://figshare.com/articles/dataset/Complexes_of_Ruthenium_II_with_Unsymmetrical_Diphosphines_and_Diphosphinomethanides_A_Way_to_Synthesize_Chiral_Metallodiphosphines/3762099
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资源简介：
Ruthenium(II) complexes with the unsymmetrical diphosphinomethanide [PPh2CHPtBu2]- containing isocyanides and chiral amines as ancillary
ligands were prepared, and the molecular structure of
[Ru(CNtBu)4{PPh2CHPtBu2}]+ was studied by X-ray
crystallography. The reactivity of the coordinated methanide toward [AuCl(PPh3)] was investigated, leading to
the stereoselective formation of the chiral metallodiphosphine [PPh2CH(AuPPh3)PtBu2].
创建时间：
2016-08-26
