Complexes of Ruthenium(II) with Unsymmetrical Diphosphines and Diphosphinomethanides. A Way to Synthesize Chiral Metallodiphosphines
收藏NIAID Data Ecosystem2026-03-06 收录
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Ruthenium(II) complexes with the unsymmetrical diphosphinomethanide [PPh2CHPtBu2]- containing isocyanides and chiral amines as ancillary ligands were prepared, and the molecular structure of [Ru(CNtBu)4{PPh2CHPtBu2}]+ was studied by X-ray crystallography. The reactivity of the coordinated methanide toward [AuCl(PPh3)] was investigated, leading to the stereoselective formation of the chiral metallodiphosphine [PPh2CH(AuPPh3)PtBu2].
创建时间：
2016-08-26
