A Synthesis of the Pseudopterosin A–F Aglycone
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0032-1316643
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资源简介:
The synthesis of the pseudopterosin A–F aglycone from 3-methylcatechol features (a) the use of asymmetric Ireland–Claisen and aryl Claisen rearrangements to install three of the four stereocentres present in the molecule and (b) an A→AB→ABC annulation strategy using ring-closing metathesis and cationic cyclisation reactions as the key steps.
提供机构:
© Georg Thieme Verlag
创建时间:
2012-09-06



