Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)<sub>2</sub>B(CO)]<sup>+</sup> Stabilized by Three Neutral Ligands
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资源简介：
A borylene cation stabilized by bis(silylene) and carbon monoxide was prepared and structurally characterized via the reaction of bis(silylene)-stabilized bromoborylene with W(CO)6. This is the first example of a borylene cation coordinated by three neutral ligands, which can be viewed as a cationic form of a long-sought Lewis base-stabilized zerovalent boron compound. This cation can cleave dihydrogen.
创建时间：
2017-09-13
