The First Mixed-Anion Complex of a Lithium Phosphazene: Synthesis and Crystal and Solution Structure of [(LiCH<sub>2</sub>P(Ph)<sub>2</sub>NPh)·(LiOC<sub>6</sub>H<sub>2</sub>-2,6-{C(CH<sub>3</sub>)<sub>3</sub>}-4-CH<sub>3</sub>)]<sub>2</sub>
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The crystal and toluene solution structure (X-ray, 1H, 7Li, 13C,31P NMR) of a mixed-anion lithium phosphazene-phenolate, 10, is a six-rung ladder consisting of two LiPCN units fused to a central Li2O2 core, which provides insight into the function of phosphazenyl-stabilized carbanions as reagents. The mixed aggregate showed decreased reactivity toward benzaldehyde with respect to the uncomplexed anion.
创建时间：
2004-12-06
