Synthesis and Reaction of Neutral and Cationic Alkyltantalum Complexes with a Linked Cyclopentadienyl-Carboranyl Ligand
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
A trimethyltantalum complex with a Cp-carboranyl ligand was prepared via a salt metathesis reaction of TaCl2Me3 with [Li2{C5H4CMe2(C2B10H10)}(OEt2)2]. Two equivalents of carbodiimides reacted with Ta(Cp-carboranyl)Me3 to form four-membered azametallacyclic compounds with an exocyclic imine group. A Lewis base stabilized cationic species was generated by the reaction of Ta(Cp-carboranyl)Me3 with B(C6F5)3(THF).
创建时间：
2016-02-22
