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Selective Dilithiation of [Ti(η5-C5H5)(η8-C8H8)] and Subsequent Conversion into Neutral and Cationic ansa-Complexes

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Selective_Dilithiation_of_Ti_sup_5_sup_C_sub_5_sub_H_sub_5_sub_sup_8_sup_C_sub_8_sub_H_sub_8_sub_and_Subsequent_Conversion_into_Neutral_and_Cationic_i_ansa_i_Complexes/2661490
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Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2]stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidation resulted in the formation of a rare example of a cationic ansa-complex (3).
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2016-02-23
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