A Porphyrin Fused to Four Anthracenes
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https://figshare.com/articles/dataset/A_Porphyrin_Fused_to_Four_Anthracenes/2698966
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资源简介:
We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl3. This compound exhibits an intense red-shifted absorption spectrum (λmax = 1417 nm; ε = 1.2 × 105 M−1 cm−1) and a small electrochemical HOMO−LUMO gap (0.61 eV). The crystal structure shows that it forms π-stacked dimers with a short Ni···Ni distance (3.32 Å).
创建时间:
2016-02-24



