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Synthesis and Photophysical Properties of Two Strongly Fluorescent Bis(diquinaldinatoalumino)-9-silafluorenes

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Synthesis_and_Photophysical_Properties_of_Two_Strongly_Fluorescent_Bis_diquinaldinatoalumino_9_silafluorenes/2345401
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资源简介:
Two novel highly fluorescent blue light emitting compounds were synthesized: 9,9-bis­(diquinaldinatoalumino)-1,3-diphenyl-9-silafluorene (4) and 9,9-bis­(diquinaldinatoalumino)-9-silafluorene (7). Combining silafluorene and quinaldinate aluminum moieties resulted in molecules with high quantum yield efficiency both in solution (31–34%) and in the solid state (79–92%). 4 showed intense electroluminescence, 4090 cd/m2 at 15 V, and the mechanochromism of 7 was revealed.
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2016-02-18
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