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Unusual Anion−Anion Assembly inside a Macrocycle-Defined Channel in the Crystal Lattice

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https://figshare.com/articles/dataset/Unusual_Anion_Anion_Assembly_inside_a_Macrocycle_Defined_Channel_in_the_Crystal_Lattice/3278872
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资源简介:
We describe the unprecedented formation of anion channels by an uncharged, amide-based macrocyclic receptor in the crystal structure of its benzoate complex. Head-to-tail aggregation of benzoate anions by means of CH···O hydrogen bonds leads to an infinite anion chain threaded inside the macrocycle-defined channel.
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2016-05-05
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