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Unusual Anion−Anion Assembly inside a Macrocycle-Defined Channel in the Crystal Lattice

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NIAID Data Ecosystem2026-03-06 收录
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We describe the unprecedented formation of anion channels by an uncharged, amide-based macrocyclic receptor in the crystal structure of its benzoate complex. Head-to-tail aggregation of benzoate anions by means of CH···O hydrogen bonds leads to an infinite anion chain threaded inside the macrocycle-defined channel.

创建时间:
2016-05-05
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