Electronic Structures of CO-Releasing Zero-Valent Metal-Organic Frameworks

We have developed a novel gas-phase approach to unique, low-valent metal-organic frameworks, exemplified by [Mo(CO)3(bipy)3/2]n (bipy = 4,4′-bipyridine) and [W(CO)3(bipy)3/2]n....我们开发了一种新型气相合成方法，用于制备独特的低价金属有机框架（low-valent metal-organic frameworks），该方法以[Mo(CO)₃(bipy)₃/2]ₙ（bipy为4,4′-联吡啶（4,4′-bipyridine））与[W(CO)₃(bipy)₃/2]ₙ为典型代表……