Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2‑Allyl-3-iodoindoles and Terminal Alkynes
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下载链接：
https://figshare.com/articles/dataset/Efficient_Carbazole_Synthesis_via_Pd_Cu_Cocatalyzed_Cross_Coupling_Isomerization_of_2_Allyl_3_iodoindoles_and_Terminal_Alkynes/2030430
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资源简介：
The Pd/Cu-cocatalyzed one-pot reaction
of 2-allyl-3-iodo-1-tosyl-1H-indoles and terminal
alkynes afforded carbazoles highly
efficiently via sequential carbon–carbon coupling, isomerization,
cyclization, and aromatization forming a benzene ring. Both Pd and
Cu are responsible for the coupling step, while K2CO3 was observed to be critical for the subsequent cyclization.
创建时间：
2015-12-17
