Microscopic rate constants, activation enthalpies (kcal mol-1) and entropies (cal mol-1 K-1) determined from the global fit of the ps-ms entire time course (at 1 and 0.1 atm CO) of CO rebinding kinetics to Tf-trHb at 20°C.
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Activation enthalpies ΔH‡ and entropies ΔS‡ were estimated from the linear Eyring plots for each rate constant ki in the temperature range 10–30°C, according to the equation: ln(hki/kBT) ) = ΔS‡/R – ΔH‡/RT, where R is the gas constant, h is Planck’s constant, and kB is Boltzmann constant.
创建时间：
2012-07-06
